期刊论文

Qiu, Ming;Yu, Ying;Ren, Zhifeng

英文

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

0002-7863

2020

142

26

11417-11427

10.1021/jacs.0c01562

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21573085, 51872108]; Wuhan Planning Project of Science and Technology [2018010401011294]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [CCNU20TS006, CCNU20ZT003]; Excellent Doctoral Dissertation Cultivation Grant from CCNU [2019YBZZ074]; National Key Research and Development Program of China [2017YFA0403400]

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Oxygen-bearing copper (OBC) has been widely studied for enabling the C-C coupling of the electrocatalytic CO(2) reduction reaction (CO(2)RR) since this is a distinctive hallmark of strongly correlated OBC systems and may benefit many other Cu-based catalytic processes. Unresolved problems, however, include the instability of and limited knowledge regarding OBC under realistic operating conditions, raising doubts about its role in CO(2)RR. Here, an atypical and stable OBC catalyst with a hierarchical pore and nanograin-boundary structure was constructed and was found to exhibit efficient CO(2)R...