Fabrication and Shell Optimization of Synergistic TiO2-MoO3 Core-Shell Nanowire Array Anode for High Energy and Power Density Lithium-Ion Batteries

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成果类型：

期刊论文

作者：

Wang, Chong;Wu, Lingxia;Wang, Hai;Zuo, Wenhua;Li, Yuanyuan;...

通讯作者：

Liu, Jinping

作者机构：

[Liu, Jinping; Wang, Chong] Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, Wuhan 430070, Hubei, Peoples R China.

[Liu, Jinping; Wang, Chong] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China.

[Liu, Jinping; Wang, Chong; Wang, Hai; Zuo, Wenhua; Wu, Lingxia] Cent China Normal Univ, Dept Phys, Inst Nanosci & Nanotechnol, Wuhan 430079, Hubei, Peoples R China.

[Li, Yuanyuan] Huazhong Univ Sci & Technol, Sch Opt & Elect Informat, Wuhan 430074, Peoples R China.

通讯机构：

[Liu, Jinping] W

Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, Wuhan 430070, Hubei, Peoples R China.

语种：

英文

关键词：

energy/power density;Li-ion full cell;MoO3;synergistic nanowire array;TiO2

期刊：

Advanced Functional Materials

ISSN：

1616-301X

年：

2015

卷：

期：

页码：

3524-3533

DOI：

10.1002/adfm.201500634

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51102105, 11104088]; Science Fund for Distinguished Young Scholars of Hubei Province [2013CFA023]; Youth Chenguang Project of Science and Technology of Wuhan City [2014070404010206]; Self-determined Research Funds of CCNU from the Colleges' Basic Research and Operation of MOE [CCNU14A02001]; Self-determined Innovation Foundation of Huazhong University of Science and Technology [2013027]; Wuhan University of Technology

机构署名：

本校为其他机构

院系归属：

物理科学与技术学院

摘要：

A novel synergistic TiO2-MoO3(TO-MO) core-shell nanowire array anode has been fabricated via a facile hydrothermal method followed by a subsequent controllable electrodeposition process. The nano-MoO3shell provides large specific capacity as well as good electrical conductivity for fast charge transfer, while the highly electrochemically stable TiO2nanowire core (negligible volume change during Li insertion/desertion) remedies the cycling instability of MoO3shell and its array further provides a 3D scaffold for large amount electrodeposition of MoO3. In combination of the unique electrochemica...

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Fabrication and Shell Optimization of Synergistic TiO2-MoO3 Core-Shell Nanowire Array Anode for High Energy and Power Density Lithium-Ion Batteries

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