We study the concentration and multiplicity of weak solutions to the Kirchhoff type equation with critical Sobolev growth, -(epsilon(2)a + epsilon b integral(R3) vertical bar del u vertical bar(2))del u + V(z)u = f(u) + u(5) in R-3, u is an element of H-1(R-3), u > 0 in R-3, where e is a small positive parameter and a, b > 0 are constants, f is an element of C-1(R+, R) is subcritical, V : R-3 -> R is a locally Holder continuous function. We first prove that for epsilon(0) > 0 sufficiently small, the above problem has a weak solution u(epsilon) with exponential decay at infinity. Moreover, u(ep...