期刊论文

Xing, Zhuo;Qiu, M

英文

催化学报

0253-9837

2024

63

8

154-163

10.1016/S1872-2067(24)60086-0

National Key Research and Development Program of China [2022YFB3803600]; National Natural Science Foun-dation of China [U20A20246]; Shandong Provincial Natural Science Foundation [ZR2020QB133]; Fundamental Research Funds for the Central Universities [CCNU22JC017, CCNU24JC013]

本校为第一且通讯机构

Using interface engineering, a highly efficient catalyst with a shell@core structure was successfully synthesized by growing an amorphous material composed of Ni, Mo, and P on Cu nanowires (NiMoP@CuNWs). This catalyst only requires an overpotential of 35 mV to reach a current density of 10 mA cm-2. The exceptional hydrogen evolution reaction (HER) activity is attributed to the unique amorphous rod-like nature of NiMoP@CuNWs, which possesses a special hydrophilic feature, enhances mass transfer, promotes effective contact between the electrode and electrolyte solution, and exposes more active s...

电化学析氢(HER)是解决能源危机和环境问题的有效手段之一.目前的研究主要聚焦于强酸或强碱电解质的电解池,然而这样的工作环境对电解池和电催化剂的长期稳定性构成了挑战.相比之下,在中性溶液中电解水制氢则具有环境友好、可持续和性价比高等特点,更具实际应用价值.然而,相较于在酸性或碱性电解液中广泛研究的催化剂,目前对中性HER催化剂的研究尚显不足.在HER过程中,过渡金属磷化物(TMPs)的金属位点和P位点作为氢化物和质子的受体可以发挥协同作用.其中,实验和理论研究结果证明,Ni-P化合物在酸性和碱性电解液中具有优异HER性能.考虑到中性电解液中反应动力学更加缓慢,还需要额外引入金属位点来...