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Sodium ion insertion in hollow carbon nanowires for battery applications

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成果类型:
期刊论文
作者:
Cao, Yuliang*;Xiao, Lifen;Sushko, Maria L.;Wang, Wei;Schwenzer, Birgit;...
通讯作者:
Cao, Yuliang
作者机构:
[Xiao, Jie; Sushko, Maria L.; Wang, Wei; Saraf, Laxmikant V.; Xiao, Lifen; Yang, Zhengguo; Cao, Yuliang; Schwenzer, Birgit; Liu, Jun; Nie, Zimin] Pacific NW Natl Lab, Richland, WA 99352 USA.
[Cao, Yuliang] Wuhan Univ, Coll Chem & Mol Sci, Hubei Key Lab Elect Power Sources, Wuhan 430072, Peoples R China.
[Xiao, Lifen] Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China.
[Cao, Yuliang] Pacific NW Natl Lab, 902 Battelle Blvd,POB 999, Richland, WA 99352 USA.
通讯机构:
[Cao, Yuliang] P
Pacific NW Natl Lab, 902 Battelle Blvd,POB 999, Richland, WA 99352 USA.
语种:
英文
关键词:
Hollow carbon nanowires;polyaniline nanowires;anode;sodium ion battery
期刊:
NANO LETTERS
ISSN:
1530-6984
年:
2012
卷:
12
期:
7
页码:
3783-3787
基金类别:
U.S. Department of Energy (DOE), Office of Electricity Delivery & Energy Reliability; Basic Energy Sciences, Division of Materials Sciences and EngineeringUnited States Department of Energy (DOE) [KC020105-FWP12152]; DOEUnited States Department of Energy (DOE) [DE-AC05-76RL01830]
机构署名:
本校为其他机构
院系归属:
化学学院
摘要:
Hollow carbon nanowires (HCNWs) were prepared through pyrolyzation of a hollow polyaniline nanowire precursor. The HCNWs used as anode material for Na-ion batteries deliver a high reversible capacity of 251 mAh g -1 and 82.2% capacity retention over 400 charge-discharge cycles between 1.2 and 0.01 V (vs Na +/Na) at a constant current of 50 mA g -1 (0.2 C). Excellent cycling stability is also observed at an even higher charge-discharge rate. A high reversible capacity of 149 mAh g -1 also can be obtained at a current rate of 500 mA g -1 (2C). Th...

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