期刊论文

Zhang, Lizhi

英文

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

0002-7863

2013

135

42

15750-15753

10.1021/ja4092903

National Basic Research Program of China (973 Program)National Basic Research Program of China [2013CB632402, 2011CB921404]; National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21073069, 91023010, 21177048]; FDA Nanotechnology CORES Program; Office of Cosmetics and Colors, CFSAN/FDA

本校为第一且通讯机构

We demonstrate that BiOCl single-crystalline nanosheets possess surface structure-dependent molecular oxygen activation properties under UV light. The (001) surface of BiOCl prefers to reduce O2 to ·O 2- through one-electron transfer, while the (010) surface favors the formation of O22- via two-electron transfer, which is cogoverned by the surface atom exposure and the situ generated oxygen vacancy characteristics of the (001) and (010) surfaces un...