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Fe@Fe2O3 core-shell nanowires as iron reagent. 4. Sono-Fenton degradation of pentachlorophenol and the mechanism analysis

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成果类型:
期刊论文
作者:
Luo, Tao;Ai, Zhihui*;Zhang, Lizhi
通讯作者:
Ai, Zhihui
作者机构:
[Luo, Tao; Zhang, Lizhi; Ai, Zhihui] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
通讯机构:
[Ai, Zhihui] C
Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
语种:
英文
期刊:
Journal of Physical Chemistry C
ISSN:
1932-7447
年:
2008
卷:
112
期:
23
页码:
8675-8681
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
In this study, a novel sono-Fenton system based on Fe@Fe2O 3 core-shell nanowires was used to degrade a recalcitrant pollutant, pentachlorophenol (PCP). We studied the influence of the pH value and the atmosphere on the degradation efficiency and the production of oxidative free radicals (such as ·OH radicals). The intermediates and the final products were determined for the analysis of the possible pathway of the decomposition. We found that this sono-Fenton system was effective for oxidizing PCP. The results help to the understanding the synergistic mechanism of the Fe@Fe 2O3 core-she...

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