期刊论文

Shi, De-Qing;Chen, JR

英文

ChemCatChem

1867-3880

2023

15

23

e202301068-

10.1002/cctc.202301068

<italic>We are grateful to the financial support from the Nation Key Ramp;D Program of China (2022YFA1506100), the National Natural Science Foundation of China (21971081, 22171099, 21820102003, 91956201, 22203034, 22271111, and 92256301), the Region Joint [2022YFA1506100]; Nation Key Ramp;D Program of China [21971081, 22171099, 21820102003, 91956201, 22203034, 22271111, 92256301]; National Natural Science Foundation of China [U21 A20384]; Region Joint Funds of the National Natural Science Foundation of China [jxsq2023102004]; Double-Thousand Talents Plan of Jiangxi Province [2021YB02, B17019]; Open Research Fund of School of Chemistry and Chemical Engineering, Henan Normal University

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Radical Cross‐CouplingA copper‐catalyzed enantioselective three‐component radical relay 1,2‐alkylesterification of 1,3‐dienes using cycloalkyl hydroperoxides and carboxylic acids was reported. This protocol features broad substrate scope and good functional group tolerance with respect to each component, providing practical access to a variety of distally keto‐functionalized chiral allylic esters with high enantioselectivity under mild and redox‐neutral conditions. Abstract Transition‐metal‐catalyzed radical relay cross‐coupling react...