State Administration of Foreign Experts Affairs#&#&#B17019
Ministry of Education of the People's Republic of China#&#&#B17019
Department of Science and Technology, Hubei Provincial People's Government#&#ߡAHB047
Central China Normal University#&#ߣYBZZ014
National Natural Science Foundation of China#&#�#&#�#&#�#&#�#&#�#&#�
机构署名：
本校为第一且通讯机构
院系归属：
化学学院
摘要：
A visible light photoredox-promoted and nitrogen radical catalyzed [3 + 2] cyclization of vinylcyclopropanes and N-tosyl vinylaziridines with alkenes is developed. Key to the success of this process is the use of the readily tunable hydrazone as a nitrogen radical catalyst. Preliminary mechanism studies suggest that the photogenerated nitrogen radical undergoes reversible radical addition to the vinylcyclopropanes and N-tosyl vinylaziridines to enable their ring-opening C-C...
