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Enantioselective Radical Carbocyanation of 1,3-Dienes via Photocatalytic Generation of Allylcopper Complexes

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成果类型:
期刊论文
作者:
Lu, Fu-Dong;Lu, Liang-Qiu;He, Gui-Feng;Bai, Jun-Chuan;Xiao, Wen-Jing
通讯作者:
Wen-Jing Xiao
作者机构:
[Lu, Fu-Dong; Lu, Liang-Qiu; Bai, Jun-Chuan; Xiao, Wen-Jing; He, Gui-Feng] Cent China Normal Univ, Coll Chem, CCNU uOttawa Joint Res Ctr, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
[Lu, Liang-Qiu] Chinese Acad Sci, Lanzhou Inst Chem Phys LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China.
[Xiao, Wen-Jing] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China.
通讯机构:
[Xiao, W.-J.] C
CCNU-uOttawa Joint Research Centre, 152 Luoyu Road, China
语种:
英文
期刊:
Journal of the American Chemical Society
ISSN:
0002-7863
年:
2021
卷:
143
期:
11
页码:
4168-4173
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21822103, 21820102003, 21822303, 21772052, 21772053, 21572074, 21472057]; Program of Introducing Talents of Discipline to Universities of China (111 Program) [B17019]; Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2017AHB047]; Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis
机构署名:
本校为第一机构
院系归属:
化学学院
摘要:
1,3-Dienes are readily available feedstocks that are widely used in the laboratory and industry. However, the potential of converting 1,3-dienes into value-added products, especially chiral products, has not yet been fully exploited. By synergetic photoredox/copper catalysis, we achieve the first visible-light-induced, enantioselective carbocyanation of 1,3-dienes by using carboxylic acid derivatives and trimethylsilyl cyanide. Under mild and neutral conditions, a diverse range of chiral allyl cyanides are produced in generally good efficiency and with high enantioselectivity from bench-stable...

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