期刊论文

Xiao, Wen-Jing;Chen, JR

英文

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

0002-7863

2024

146

2

1410-1422

10.1021/jacs.3c10439

National Natural Science Foundation of China [2023YFA1507203]; National Key R&D Program of China [21971081, 22171099, 91856119, 91956201, 21820102003]; National Natural Science Foundation of China [2022YFA1506100]; Nation Key R&D Program of China [LQ20B020010]; Zhejiang Natural Science Foundation [2021YB02, 2022013301015173]; Open Research Fund of School of Chemistry and Chemical Engineering, Henan Normal University [jxsq2023102004]; Double-Thousand Talents Plan of Jiangxi Province [B17019]; Program of Introducing Talents of Discipline to Universities of China

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Alkene radical ions constitute an integral and unique class of reactive intermediates for the synthesis of valuable compounds because they have both unpaired spins and charge. However, relatively few synthetic applications of alkene radical anions have emerged due to a dearth of generally applicable and mild radical anion generation approaches. Precise control over the chemo- and stereoselectivity in alkene radical anion-mediated processes represents another long-standing challenge due to their high reactivity. To overcome these issues, here, we develop a new redox-neutral strategy that seamle...