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Protocatechuic Acid Promoted Alachlor Degradation in Fe(III)/H2O2Fenton System

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成果类型:
期刊论文
作者:
Qin, Yaxin;Song, Fahui;Ai, Zhihui;Zhang, Pingping;Zhang, Lizhi*
通讯作者:
Zhang, Lizhi
作者机构:
[Zhang, Lizhi; Qin, Yaxin; Song, Fahui; Ai, Zhihui; Zhang, Pingping] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Inst Environm Chem, Minist Educ,Coll Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Zhang, Lizhi] C
Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Inst Environm Chem, Minist Educ,Coll Chem, Wuhan 430079, Peoples R China.
语种:
英文
期刊:
Environmental Science & Technology
ISSN:
0013-936X
年:
2015
卷:
49
期:
13
页码:
7948-7956
基金类别:
National Natural Science Funds for Distinguished Young ScholarsNational Natural Science Foundation of China (NSFC)National Science Fund for Distinguished Young Scholars [21425728]; National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21173093, 21177048, 21273088, 21477044]; Key Project of Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2013CFA114]; Self-Determined Research Funds of CCNU from the Colleges' Basic Research and Operation of MOE [CCNU14Z01001, CCNU14KFY002]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
In this study, we demonstrate that protocatechuic acid (PCA) can significantly promote the alachlor degradation in the Fe(III)/H2O2 Fenton oxidation system. It was found that the addition of protocatechuic acid could increase the alachlor degradation rate by 10 000 times in this Fenton oxidation system at pH = 3.6. This dramatic enhancement of alachlor degradation was attributed to the complexing and reduction abilities of protocatechuic ligand, which could form stable complexes with ferric ions to prevent their precipitation and also accelerat...

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