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Nanocrystalline ZnMn2O4 as a novel lithium-storage material

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成果类型:
期刊论文
作者:
Yang, Yanyan;Zhao, Yanqiang;Xiao, Lifen*;Zhang, Lizhi
通讯作者:
Xiao, Lifen
作者机构:
[Zhao, Yanqiang; Zhang, Lizhi; Yang, Yanyan; Xiao, Lifen] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Xiao, Lifen] C
Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Anode;Lithium ion batteries;Polymer-pyrolysis;ZnMn2O4 nanocrystals
期刊:
Electrochemistry Communications
ISSN:
1388-2481
年:
2008
卷:
10
期:
8
页码:
1117-1120
基金类别:
National Basic Research Program of China [2007CB613301]; Grant 2007CB613301), National Science Foundation of China [20503009, 20777026]; New Century Excellent Talents in University [NCET-07-0352]; Ministry of Education of China [108097]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Nanocrystalline ZnMn2O4 is prepared by a polymer-pyrolysis route and used as a novel anode for lithium ion batteries. XRD and HRTEM studies reveal that the products are highly phase-pure and 30-60 nm in size. Galvanostatic cycling of ZnMn2O4 electrode at 100 mA g-1 (about 0.52 mA cm-2) between 0.01 and 3.0 V up to 50 cycles exhibits almost stable cycling performance between 10 and 50 cycles with only an average capacity fade of 0.20% per cycle and the electrode still maintains a capacity of 569 mAh g-1...

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