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Propeller-shape isomers with turn-on through-space charge transfer for solution-processed non-doped organic light-emitting diodes

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成果类型:
期刊论文
作者:
Li, Jiale;Zhou, Ling;He, Jiawei;Xue, Qin;Xu, Liang;...
通讯作者:
Xue, Qin(xueqin@mail.ccnu.edu.cn)
作者机构:
[He, Jiawei; Li, Jiale; Zhou, Ling; Xue, Qin; Xie, Guohua] Wuhan Univ, Sauvage Ctr Mol Sci, Dept Chem, Hubei Key Lab Organ & Polymer Optoelect Mat, Wuhan 430072, Peoples R China.
[Xue, Qin] Cent China Normal Univ, Dept Phys Sci & Technol, Wuhan 430079, Peoples R China.
[Xu, Liang; Xie, Guohua] Shantou Univ, Dept Chem, Key Lab Preparat & Applicat Ordered Struct Mat Gua, Shantou 515063, Guangdong, Peoples R China.
[Xie, Guohua] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Wuhan 430074, Peoples R China.
通讯机构:
[Qin Xue] D
[Guohua Xie] S
Department of Physical Science and Technology, Central China Normal University, Wuhan 430079, People’s Republic of China<&wdkj&>Sauvage Center for Molecular Sciences, Hubei Key Lab on Organic and Polymeric Optoelectronic Materials, Department of Chemistry, Wuhan University, Wuhan 430072, People’s Republic of China<&wdkj&>Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong 515063, People’s Republic of China<&wdkj&>Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, People’s Republic of China
语种:
英文
关键词:
Thermally activated delayed fluorescence;Through -space charge transfer;Aggregation -induced emission;Solution -processed OLEDs
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2023
卷:
452
页码:
139120
基金类别:
The authors acknowledge the financial support from the National Natural Science Foundation of China (Nos. 51873159 and 62175189). G. X. acknowledged the funding support from the Program for Promoting Academic Collaboration and Senior Talent Fostering between China and Canada, Australia, New Zealand and Latin America (2021-109), the Open Fund of Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University (No. KLPAOSM202003), and the Open Project Program of Wuhan National Laboratory for Optoelectronics (No. 2019WNLOKF015). The numerical calculations in this paper have been done on the supercomputing system in the Supercomputing Center of Wuhan University.
机构署名:
本校为其他机构
院系归属:
物理科学与技术学院
摘要:
Purely organic thermally activated delayed fluorescence (TADF) emitters have developed rapidly in the last decade. Recently, the TADF materials with through-space charge transfer (TSCT) attract great attention due to the ease of tuning the optoelectronic properties for organic light-emitting diodes (OLEDs). Herein, we report the design and synthesis of three propeller-shape emitters via isomer engineering, which are named as TRZ-o-SDMAC, TRZ-m-SDMAC and TRZ-p-SDMAC respectively. Surprisingly, TRZ-o-SDMAC and TRZ-m-SDMAC simultaneously exhibit T...

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