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One-Pot Three-Component Method for the Synthesis of Polyfunctional Cyclopropanes

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成果类型:
会议论文
作者:
Wen-Ming Shu;Jun-Rui Ma;An-Xin Wu
作者机构:
[Wen-Ming Shu; Jun-Rui Ma; An-Xin Wu] Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry,Central China Normal University
语种:
英文
关键词:
Cyclopropanes;One-Pot;Three-Component.
年:
2014
页码:
165
会议名称:
中国化学会第29届学术年会
会议论文集名称:
中国化学会第29届学术年会摘要集-第07分会:有机化学
会议时间:
2014-08-04
会议地点:
北京
会议赞助商:
中国化学会
机构署名:
本校为第一机构
院系归属:
化学学院
摘要:
Cyclopropane unit as a fundamental structure performs a key role in a wide range of natural products as well as biological active molecules.[1] Because of the importance of cyclopropanes, enormous effort has therefore been devoted to this activity, and considerable methods have been developed for the construction of cyclopropane derivatives.[2] Generally, this small and highly strained skeleton is established by the addition of a carbine to an electron-deficient olefin.[3] In addition, Michael-initiated ring-closure procedures are also good approaches for the synthesis of multifunctionalized c...

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