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Charge Shielding Effect of Sodium Ions in Improving The Hydrophobicity and Performance of Co/Na-SSZ-13 Zeolite for Passive NOx Adsorber

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成果类型:
期刊论文
作者:
Chen, Zhen*;Tao, Qian;Yang, Li;Qin, Yuanhang;Wang, Cunwen;...
通讯作者:
Chen, Zhen;Qin, YH;Guo, YB
作者机构:
[Tao, Qian; Chen, Zhen; Yang, Li; Wang, Cunwen; Qin, Yuanhang] Wuhan Inst Technol, Sch Chem Engn & Pharm, Key Lab Green Chem Proc, Hubei Key Lab Novel React & Green Chem Technol,Min, Wuhan 430205, Peoples R China.
[Guo, YB; Guo, Yanbing] Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Guo, YB ] C
[Chen, Z; Qin, YH ] W
Wuhan Inst Technol, Sch Chem Engn & Pharm, Key Lab Green Chem Proc, Hubei Key Lab Novel React & Green Chem Technol,Min, Wuhan 430205, Peoples R China.
Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
cold start;Co/Na-SSZ-13 zeolite;hydrophobicity;NOx;passive NOx adsorber
期刊:
Advanced Functional Materials
ISSN:
1616-301X
年:
2024
基金类别:
National Natural Science Foundation of China; Science Foundation of Wuhan Institute of Technology [K202204]; [52000084]; [52370118]
机构署名:
本校为通讯机构
院系归属:
化学学院
摘要:
With increasingly stringent regulations, the reduction of NOx emissions during vehicle cold start is a major challenge. Pd-modified zeolites are considered as the most promising passive NOx adsorber (PNA) for cold start NOx control. Nevertheless, the scarcity and the high cost of Pd limit its practical application. Herein, a non-precious metal modified Co/Na-SSZ-13 zeolite for low-temperature NOx adsorption is reported. This one-pot synthesized Co/Na-SSZ-13 exhibits an extraordinary NOx storage capacity (212 mu mol g(cat)(-1)) under humid conditions (3% H2O v/v), which is more than double that...

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