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Extended measurement of the v2(1-←0+) band of H3O+ by mid-infrared diode laser spectroscopy

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成果类型:
期刊论文
作者:
Zheng, Rui;Wang, Rui-Bo;Li, Song;Huang, Guang-Ming;Duan, Chuan-Xi
通讯作者:
Zheng, R.
作者机构:
[Zheng, Rui; Wang, Rui-Bo; Li, Song; Huang, Guang-Ming; Duan, Chuan-Xi] College of Physical Science and Technology, Huazhong Normal University, Wuhan 430079, China
通讯机构:
[Zheng, R.] C
College of Physical Science and Technology, , Wuhan 430079, China
语种:
英文
期刊:
中国物理快报:英文版
ISSN:
0256-307X
年:
2007
卷:
24
期:
9
页码:
2569-2571
机构署名:
本校为第一机构
院系归属:
物理科学与技术学院
摘要:
Twenty-five new R-branch lines of the v2 (1 -←0+) band of H3O+ are measured using diode laser velocity modulation spectroscopy between 1070 and 1230 cm-1. The H3O+ ions are produced in a high voltage ac discharge with water diluted in helium. The observed lines together with all the previously published measurements are fit to the standard vibration-rotational Hamiltonian of an oblate symmetric top, yielding a set of improved molecular constants. All the sextic centrifugal distortion constants for both 0+ and 1- states are determined precisely...

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