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Persulfate activation induced by ascorbic acid for efficient organic pollutants oxidation

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成果类型:
期刊论文
作者:
Hou, Xiaojing;Zhan, Guangming;Huang, Xiaopeng;Wang, Nan;Ai, Zhihui*;...
通讯作者:
Ai, Zhihui;Zhang, Lizhi
作者机构:
[Zhang, Lizhi; Hou, Xiaojing; Wang, Nan; Huang, Xiaopeng; Ai, ZH; Zhang, LZ; Zhan, Guangming; Ai, Zhihui] Cent China Normal Univ, Inst Environm & Appl Chem, Coll Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Hubei, Peoples R China.
通讯机构:
[Ai, ZH; Zhang, LZ] C
Cent China Normal Univ, Inst Environm & Appl Chem, Coll Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Hubei, Peoples R China.
语种:
英文
关键词:
Ascorbic acid;In situ chemical oxidation;Organic pollutants;Persulfate activation
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2020
卷:
382
页码:
122355
基金类别:
Fig. 1a shows the curves of atrazine degradation with PS in the absence or presence of AA. In the absence of AA, about 14% of atrazine was degraded in the aerobic (PS/Air) or anaerobic (PS/Ar) condition within 6 h. As expected, the degradation percentage of atrazine in the presence of AA in the aerobic (AA/PS/Air) or anaerobic (AA/PS/Ar) condition reached 66% and 100%, respectively, within 6 h. All the degradation curves of atrazine obeyed pseudo-first-order kinetics (Fig. 1b). The atrazine
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
In this study, we demonstrate that ascorbic acid (AA) exhibited extremely high activity on persulfate (PS) activation (AA/PS) to produce SO4[rad]− and [rad]OH for the degradation of various organic pollutants, including atrazine, pentachlorophenol, alachlor, tetracycline, and chloramphenicol. Taken atrazine as a model natural organic micropollutants, we surprisingly found that the degradation rate constant of atrazine during PS activation in presence of AA was about 29 times larger than that in the absence of AA. The underlying mechanism of pe...

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