期刊论文

Chen, Jia-Rong

英文

ACCOUNTS OF CHEMICAL RESEARCH

0001-4842

2020

53

5

1066-1083

10.1021/acs.accounts.0c00090

We are sincerely grateful to our collaborators and co-workers for their significant contributions to this project. The authors’ work in this area was sponsored by the National Natural Science Foundation of China (91856119, 21971081, 21622201, 21820102003, 91956201, and 21772053), the Science and Technology Department of Hubei Province (2017AHB047), and the Program of Introducing Talents of Discipline to Universities of China (111 Program) (B17019).

本校为第一且通讯机构

ConspectusNitrogen-centered radicals (NCRs) are a versatile class of highly reactive species that have a longer history than the classical carbon-based radicals in synthetic chemistry. Depending on the N-hybridization and substitution patterns, NCRs can serve as electrophiles or nucleophiles to undergo various radical transformations. Despite their power, progress in nitrogen-radical chemistry is still slow compared with the popularity of carbon radicals, and their considerable synthetic potential has been largely underexplored, which is, as co...