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Aminopyridyl derivative of thiacalix[4]arene-carboxylic acid as ionizable highly selective Ag+ ionophore

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成果类型:
期刊论文、会议论文
作者:
Li, Xiong;Gong, Shu-Ling*;Yang, Wei-Ping;Li, Yan;Chen, Yuan-Yin;...
通讯作者:
Gong, Shu-Ling
作者机构:
[Li, Xiong] Huazhong Univ Sci & Technol, Natl Lab Optoelect, Wuhan 430074, Peoples R China.
[Yang, Wei-Ping; Chen, Yuan-Yin; Li, Yan; Gong, Shu-Ling] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China.
[Meng, Xiang-Gao] Huazhong Normal Univ, Coll Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Gong, Shu-Ling] W
Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China.
语种:
英文
关键词:
Thiacalix[4]arene;Ionizable ligand;Silver ionophore;Solvent extraction
期刊:
Journal of Inclusion Phenomena and Macrocyclic Chemistry
ISSN:
1388-3127
年:
2010
卷:
66
期:
1-2
页码:
179-184
会议名称:
10th International Conference on Calixarenes
会议时间:
JUL 13-16, 2009
会议地点:
Seoul, SOUTH KOREA
会议主办单位:
[Gong, Shu-Ling;Yang, Wei-Ping;Li, Yan;Chen, Yuan-Yin] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China.^[Li, Xiong] Huazhong Univ Sci & Technol, Natl Lab Optoelect, Wuhan 430074, Peoples R China.^[Meng, Xiang-Gao] Huazhong Normal Univ, Coll Chem, Wuhan 430079, Peoples R China.
出版地:
VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS
出版者:
SPRINGER
机构署名:
本校为其他机构
院系归属:
化学学院
摘要:
A novel mono-ionizable receptor 2 possessing three aminopyridyl and one carboxylic group in 1,3-alternate conformation based on thiacalix[4]arene, confirmed by single crystal X-ray analysis, was prepared. For competitive solvent extraction of alkali metal (Na+, K+ and Cs+) and some transition metal (Cu2+, Zn2+, TI+, Ag+) cations from aqueous solutions into chloroform, it was found that the introduction of proton-ionizable group (carboxylic acid moiety) into the aminopyridyl-thiacalix[4]arene derivative could f...

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