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Carbon enhanced nucleophilicity of Na3V2(PO4)3: A general approach for dendrite-free zinc metal anodes

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成果类型:
期刊论文
作者:
Wang, Sijun;Hu, Lingzi;Li, Xiaohui;Qiu, Dan;Qiu, Shunhang;...
通讯作者:
Yang, Ze;Qiu, Ming;Yu, Y
作者机构:
[Li, Xiaohui; Qiu, Shunhang; Qiu, Ming; Wang, Sijun; Yang, Ze; Qiu, Dan; Hu, Lingzi; Yu, Ying; Zhou, Qiancheng] Cent China Normal Univ, Inst Nanosci & Nanotechnol, Sch Phys Sci & Technol, Wuhan 430079, Hubei, Peoples R China.
[Deng, Wenwen] Suzhou Univ Sci & Technol, Sch Mat Sci & Engn, Suzhou 215000, Peoples R China.
[Lu, Xiaoying] Technol & Higher Educ Inst Hong Kong, Fac Sci & Technol, Hong Kong, Peoples R China.
通讯机构:
[Yu, Y ; Qiu, M; Yang, Z] C
Cent China Normal Univ, Inst Nanosci & Nanotechnol, Sch Phys Sci & Technol, Wuhan 430079, Hubei, Peoples R China.
语种:
英文
关键词:
Zinc-ion batteries;Zinc anode;Carbon enhanced nucleophilicity;Zincophilic particle regulation
期刊:
能源化学(英文)
ISSN:
2095-4956
年:
2024
卷:
91
页码:
203-212
基金类别:
National Key Research and Development Program of China [2022YFB3803600]; Fundamental Research Funds for the Central Universities [30106200463, CCNU22CJ017]; National Natural Science Foundation of China [U20A20246]; Graduate Education Innovation Grant from Central China Normal University, China [20210407032]
机构署名:
本校为第一且通讯机构
院系归属:
物理科学与技术学院
摘要:
Zincophilic property and high electrical conductivity are both very important parameters to design novel Zn anode for aqueous Zn-ion batteries (AZIBs). However, single material is difficult to exhibit zincophilic property and high electrical conductivity at the same time. Herein, originating from theoretical calculation, a zincophilic particle regulation strategy is proposed to address these limitations and carbon coated Na3V2(PO4)3 is taken as an example to be a protective layer on zinc metal (NVPC@Zn). Na3V2(PO4)3 (NVP) is a common cathode material for Zn-ion batteries, which is zincophilic....

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