Redox-neutral α-allylation of amines by combining palladium catalysis and visible-light photoredox catalysis

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成果类型：

期刊论文

作者：

Xuan, Jun;Zeng, Ting-Ting;Feng, Zhu-Jia;Deng, Qiao-Hui;Chen, Jia-Rong;...

通讯作者：

Lu, Liang-Qiu

作者机构：

[Lu, Liang-Qiu; Feng, Zhu-Jia; Deng, Qiao-Hui; Xiao, Wen-Jing; Chen, Jia-Rong; Xuan, Jun; Zeng, Ting-Ting] CCNU, CCNU uOttawa Joint Res Ctr, Key Lab Pesticide & Chem Biol, Minist Educ,Coll Chem, Wuhan 430079, Hubei, Peoples R China.

[Xiao, Wen-Jing] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin, Peoples R China.

[Xiao, Wen-Jing] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China.

[Alper, Howard] Univ Ottawa, Dept Chem, Ctr Catalysis Res & Innovat, Ottawa, ON K1N 6N5, Canada.

[Lu, Liang-Qiu] CCNU, CCNU uOttawa Joint Res Ctr, Key Lab Pesticide & Chem Biol, Minist Educ,Coll Chem, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.

通讯机构：

[Lu, Liang-Qiu] C

CCNU, CCNU uOttawa Joint Res Ctr, Key Lab Pesticide & Chem Biol, Minist Educ,Coll Chem, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.

语种：

英文

关键词：

allylic compounds;palladium;photochemistry;radicals;synthetic methods

期刊：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ISSN：

1433-7851

年：

2015

卷：

期：

页码：

1625-1628

DOI：

10.1002/anie.201409999

基金类别：

National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21232003, 21202053, 21272087]; National Basic Research Program of ChinaNational Basic Research Program of China [2011CB808603]

机构署名：

本校为第一且通讯机构

院系归属：

化学学院

摘要：

An unprecedented α-allylation of amines was achieved by combining palladium catalysis and visible-light photoredox catalysis. In this dual catalysis process, the catalytic generation of allyl radical from the corresponding π-allylpalladium intermediate was achieved without additional metal reducing reagents (redox-neutral). Various allylation products of amines were obtained in high yields through radical cross-coupling under mild reaction conditions. Moreover, the transformation was applied to the formal synthesis of 8-oxoprotoberberine derivatives which show pote...

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Redox-neutral α-allylation of amines by combining palladium catalysis and visible-light photoredox catalysis

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