The dynamics of a rarefied gas in a finite channel with the same temperatures and opposite velocities is a fundamental problem in kinetic theory. The relative motion of the planar boundaries can induce a non-equilibrium state which is referred to as the Couette flow. In this paper, we demonstrate that the unsteady Couette flow for the Boltzmann equation in 3D finite channel time asymptotically converges to the 1D steady state constructed in Duan et al. (2022), we also prove the exponential time decay rate as a byproduct. The vali...