Synthesis of bimetallic 4-PySI-Pd@Cu(BDC) via open metal site Cu-MOF: Effect of metal and support of Pd@Cu-MOFs in H2 generation from formic acid

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成果类型：

期刊论文

作者：

Alamgholiloo, Hassan;Zhang, Shengbo;Ahadi, Arefeh;Rostamnia, Sadegh*;Banaei, Reza;...

通讯作者：

Rostamnia, Sadegh;Liu, Xiao;Shokouhimehr, Mohammadreza

作者机构：

[Banaei, Reza; Rostamnia, Sadegh; Alamgholiloo, Hassan; Ahadi, Arefeh] Univ Maragheh, Fac Sci, Dept Chem, ONG, POB 55181-83111, Maragheh, Iran.

[Liu, Xiao] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Hubei, Peoples R China.

[Zhang, Shengbo] Tianjin Univ, Sch Chem Engn & Technol, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China.

[Li, Zhongcheng] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, State Key Lab Base Ecochem Engn, Qingdao 266042, Peoples R China.

[Shokouhimehr, Mohammadreza] Seoul Natl Univ, Res Inst Adv Mat, Dept Mat Sci & Engn, Seoul 08826, South Korea.

通讯机构：

[Rostamnia, Sadegh] U

[Liu, Xiao] C

[Shokouhimehr, Mohammadreza] S

Univ Maragheh, Fac Sci, Dept Chem, ONG, POB 55181-83111, Maragheh, Iran.

Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Hubei, Peoples R China.

语种：

英文

关键词：

Bimetallic metal-organic framework;Formic acid dehydrogenation;Heterogeneous catalysis;[email protected]

期刊：

Molecular Catalysis

ISSN：

2468-8231

年：

2019

卷：

467

页码：

30-37

DOI：

10.1016/j.mcat.2019.01.031

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [U1662109]; Iran National Science Foundation (INSF)Iran National Science Foundation (INSF); Program of Introducing Talents of Discipline to Universities of China (111 program) [B17019]

机构署名：

本校为通讯机构

院系归属：

化学学院

摘要：

Catalysts based on palladium ions grafted on Schiff-base decorated OMS-Cu(BDC) pore cage were prepared and their catalytic performance in the hydrogen generation from formic acid was studied. The effects of the porous MOF structure and Schiff-based group presented around the Pd ions play important roles in stabilizing the Pd ions, providing strong interaction between the MOF support and Pd site. The Pd-Schiff base complex grafted on Cu-MOF exhibits excellent catalytic activity to produce 147 mL of gas (H2 + CO2) with the turnover frequency (TOF...

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Synthesis of bimetallic 4-PySI-Pd@Cu(BDC) via open metal site Cu-MOF: Effect of metal and support of Pd@Cu-MOFs in H2 generation from formic acid

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