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Visible light promoted Fe3S4 Fenton oxidation of atrazine

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成果类型:
期刊论文
作者:
Shi, Yanbiao;Wang, Xiaobing;Liu, Xiufan;Ling, Cancan;Shen, Wenjuan;...
通讯作者:
Zhang, Lizhi
作者机构:
[Ling, Cancan; Zhang, Lizhi; Liu, Xiufan; Shi, Yanbiao; Wang, Xiaobing; Shen, Wenjuan] Cent China Normal Univ, Inst Environm & Appl Chem, Key Lab Pesticide & Chem Biol Minist Educ, Wuhan 430079, Peoples R China.
[Shen, Wenjuan] Wuhan Polytech Univ, Coll Chem & Environm Engn, Wuhan 430023, Peoples R China.
通讯机构:
[Zhang, Lizhi] C
Cent China Normal Univ, Inst Environm & Appl Chem, Key Lab Pesticide & Chem Biol Minist Educ, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Atrazine degradation;Heterogeneous Fenton reaction;Reusability;Surface iron redox cycle;Visible light irradiation
期刊:
Applied Catalysis B: Environmental
ISSN:
0926-3373
年:
2020
卷:
277
页码:
119229
基金类别:
CRediT authorship contribution statement Yanbiao Shi: Conceptualization, Investigation, Writing - original draft. Xiaobing Wang: Formal analysis, Resources. Xiufan Liu: Visualization. Wenjuan Shen: Software. Lizhi Zhang: acquisition, Project administration, Supervision, Writing - review & editing.
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
We demonstrate that visible light irradiation can promote Fe3S4 Fenton oxidation of atrazine. The visible light irradiation could increase the atrazine Fenton degradation rate by 4.9 times. The enhanced atrazine degradation activity under visible light was attributed to the higher surficial Fe(II)/Fe(III) ratio of Fe3S4 and the efficient surface iron redox cycle triggered by visible light. Experimental results revealed that the operando formation of FeOOH on the Fe3S4 surface blocked the iron redox cycle and inhibited the H2O2 decomposition, ac...

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