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Bifunctional S, N-Codoped carbon dots-based novel electrochemiluminescent bioassay for ultrasensitive detection of atrazine using activated mesoporous biocarbon as enzyme nanocarriers

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成果类型:
期刊论文
作者:
Wu, Yunqing;Chen, Yuxin;Zhang, Shiqin;Zhang, Lizhi;Gong, Jingming*
通讯作者:
Gong, Jingming
作者机构:
[Zhang, Shiqin; Zhang, Lizhi; Chen, Yuxin; Gong, Jingming; Wu, Yunqing] Cent China Normal Univ, Int Joint Res Ctr Intelligent Biosensing Technol, Coll Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Hubei, Peoples R China.
通讯机构:
[Gong, Jingming] C
Cent China Normal Univ, Int Joint Res Ctr Intelligent Biosensing Technol, Coll Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Hubei, Peoples R China.
语种:
英文
关键词:
Atrazine;Bifunctional S;Dissolved oxygen;Electrochemiluminescent bioassay;Mesoporous bicarbons;N-codoped carbon dots
期刊:
Analytica Chimica Acta
ISSN:
0003-2670
年:
2019
卷:
1073
页码:
45-53
基金类别:
National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21475050, 21777052]; National Key R&D Program of China [2018YFC1802003]; Self-determined Research Funds of CCNU from the Colleges' Basic Research and Operation of MOE [CCNU18TS013]; Program of Introducing Talents of Discipline to Universities of China (111 program) [B17019]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
A novel and ultrasensitive electrochemiluminescent (ECL) bioassay has been developed for the detection of atrazine (ATZ), whereby bifunctional S, N-codoped carbon dots (S, N-CDs) and activated mesoporous bicarbons (BCs) have been innovatively integrated to synergistically amplify the ECL signal. When endogenous dissolved O2 is used as a coreactant, its sluggish reduction hinders the enhancement of ECL intensity of the luminophore, thus restricting its further application in bioanalysis. Here, bifunctional S, N-CDs severe as not only the ECL lum...

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