Phosphorus-containing agrochemicals have made a major contribution to the advancement of agriculture in China. Current status about production and usages of organophosphorus agrochemicals in China is reviewed in this article. Development of new organophosphorus agrochemicals including insecticide, herbicide, and anti-TMV agent in recent years is introduced. Recent progress in research and development of α -(Substituted phenoxyacetoxy)alkylphosphonates is then described: α -(Substituted phenoxyacetoxy)alkylphosphonate II as a kind of potential...