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Glutathione modified Ag nanoparticles as efficient detector for pyrimethanil.

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成果类型:
期刊论文
作者:
Zhang, Siyun;Hu, Ren;Li, Haibing*
通讯作者:
Li, Haibing
作者机构:
[Li, Haibing; Hu, Ren; Zhang, Siyun] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol CCNU, Minist Educ, Wuhan 430079, Hubei, Peoples R China.
通讯机构:
[Li, Haibing] C
Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol CCNU, Minist Educ, Wuhan 430079, Hubei, Peoples R China.
语种:
英文
关键词:
Ag nanoparticles;glutathione modification;pyrimethanil detection;pesticide
期刊:
Nanotechnology
ISSN:
0957-4484
年:
2019
卷:
30
期:
11
页码:
115502
基金类别:
National Key Research and Development Program of China [SQ2018YFD020002]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21772055, 21572076]; Nature Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2018CFB534]; 111 ProjectMinistry of Education, China - 111 Project [B17019]; self-determined research funds of CCNU from the colleges' basic research and operation of MOE
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
This work reports on glutathione modified Ag nanoparticles (GSH-Ag NPs) as a chemosensor for detecting pyrimethanil in an aqueous medium. The GSH-Ag NPs were expediently obtained by reducing AgNO3 with NaBH4 and modified with glutathione based on the Ag-S bond. The rapid discrimination for pyrimethanil from other pesticides exhibited the high selectivity of GSH-Ag NPs, then the selectivity was proved by 1H NMR, FT-IR and computational simulation. Based on the good properties of localized surface plasmon resonance, the selective recognition was ...

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