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Oxygen vacancy promoted H2O activation over K+-doped ε-MnO2 for low-temperature HCHO oxidation

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成果类型:
期刊论文
作者:
Wang, Fanyu;Feng, Yaqin;Wang, Zhongsen;Liu, Yi;Gu, Huayu;...
通讯作者:
Liu, Xiao(liuxiao71@ccnu.edu.cn)
作者机构:
[Gu, Huayu; Feng, Yaqin; Liu, Yi; Wang, Fanyu; Wang, Zhongsen; Liu, Xiao] Cent China Normal Univ, Coll Chem, Engn Res Ctr Photoenergy Utilizat Pollut Control &, Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Xiao Liu] E
Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, PR China
语种:
英文
关键词:
Water activation;Oxygen vacancy;Low -Temperature HCHO Oxidation;K plus -doped?-MnO2
期刊:
Applied Surface Science
ISSN:
0169-4332
年:
2023
卷:
624
页码:
157127
基金类别:
CRediT authorship contribution statement Fanyu Wang: Writing – original draft. Yaqin Feng: Formal analysis. Zhongsen Wang: . Yi Liu: . Huayu Gu: . Xiao Liu: Project administration, acquisition.
机构署名:
本校为第一机构
院系归属:
化学学院
摘要:
H2O activation plays a crucial role in the oxidation process of HCHO, which can create active hydroxyl to attack HCHO molecules and enhance the catalytic activity. Therefore, the construction of highly active sites for H2O activation to accelerate the reaction rate is required. Herein, we constructed and regulated the surface oxygen vacancies over epsilon-MnO2 with the aid of K doping to activate H2O through a simple hydrothermal method. The role of oxygen vacancy produced by K+ doping for H2O activation in HCHO removal was investigated by various technologies, including XPS, TPD, TPSR, and in...

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