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Synthesis of new meso-tetraarylporphyrins bearing cardanol and further transformation of the unsaturated chains

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成果类型:
期刊论文
作者:
Guo, Ying-Cen;Xiao, Wen-Jing;Mele, Giuseppe*;Martina, Francesca;Margapoti, Eleonora;...
通讯作者:
Mele, Giuseppe
作者机构:
[Mele, Giuseppe] Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China.
Cent China Normal Univ, Coll Chem, Wuhan 430079, Hubei, Peoples R China.
Univ Lecce, Dipartimento Ingn Innovaz, I-73100 Lecce, Italy.
Univ Fed Ceara, Dept Quim Organ & Inorgan, BR-60455760 Fortaleza, Ceara, Brazil.
通讯机构:
[Mele, Giuseppe] C
Cent China Normal Univ, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China.
语种:
英文
关键词:
cardanol;3-n-pentadecylphenol;porphyrins;metalloporphyrins;epoxy
期刊:
Journal of Porphyrins and Phthalocyanines
ISSN:
1088-4246
年:
2006
卷:
10
期:
8
页码:
1071-1079
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
This paper deals with the synthesis of a new hybrid meso-tetraarylporphyrin-cardanol with the cardanol bearing an unsaturated chain. Cardanol is a renewable, natural, widely available and relatively low-cost material obtained as a by-product of the cashew industry which provides cashew kernels for edible use. The unsaturation in the chain in the new hybrid meso-tetraaryiporphyrin-cardanol leads to chemical and physico-chemical properties which are different from the saturated derivatives. The unsaturation also allows preparation of the corresponding epoxy compounds as well as self-metathesis d...

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