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Efficient Cu(II) removal with boronated zero-valent iron via inhibition of oxygen adsorption and enhanced electron transfer

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成果类型:
期刊论文
作者:
Zhang, Xu;Yao, Zixin;Gao, Yan;Yan, Shuang;Peng, Xing;...
通讯作者:
Peng, X;Shen, WJ
作者机构:
[Peng, X; Peng, Xing; Zhang, Xu] Cent China Normal Univ, Inst Environm & Appl Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
[Yao, Zixin; Gao, Yan; Shen, Wenjuan] Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
[Yan, Shuang] Wuhan Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430081, Peoples R China.
通讯机构:
[Peng, X ] C
[Shen, WJ ] W
Cent China Normal Univ, Inst Environm & Appl Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
Wuhan Polytech Univ, Sch Chem & Environm Engn, Wuhan 430023, Peoples R China.
语种:
英文
关键词:
Cu(II) reduction;Zero-valent iron;Boric acid;Oxygen adsorption;Electron transfer
期刊:
Applied Surface Science
ISSN:
0169-4332
年:
2024
卷:
654
页码:
159466
基金类别:
CRediT authorship contribution statement Xu Zhang: Conceptualization, Data curation, Software, Writing – original draft, Writing – review & editing. Zixin Yao: Data curation, Formal analysis, Investigation, Methodology, Software. Yan Gao: Data curation, Investigation, Methodology. Shuang Yan: Software. Xing Peng: Conceptualization, acquisition, Writing – review & editing. Wenjuan Shen: Conceptualization, acquisition, Supervision, Writing – review & editing.
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
The inhibition of electron transfer by the iron oxide passivation layer and the competition of oxygen for electrons limited the efficiency of heavy metal removal by zero-valent iron reduction. Herein we synthesized micron zero-valent iron modified with boric acid by mechanical ball milling, and demonstrated its enhanced copper ions removal performance. Compared to pristine ZVI, B-ZVI is approximately 2.6 times more efficient in the removal of copper. Interestingly, copper removal was significantly inhibited under air atmosphere for pristine ZVI. However, for B-ZVI, copper removal efficiency wa...

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