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Nitrate promoted defluorination of perfluorooctanoic acid in UV/sulfite system: Coupling hydrated electron/reactive nitrogen species-mediated reduction and oxidation

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成果类型:
期刊论文
作者:
Yuan, Yijin;Feng, Lizhen;He, Xianqin;Wu, Mengsi;Ai, Zhihui;...
通讯作者:
Gong, Jingming(jmgong@mail.ccnu.edu.cn)
作者机构:
[Feng, Lizhen; Zhang, Lizhi; Gong, Jingming; Yuan, Yijin; Wu, Mengsi; He, Xianqin; Ai, Zhihui] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Inst Environm & Appl Chem,Minist Educat, Wuhan 430079, Peoples R China.
通讯机构:
[Jingming Gong] K
Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Environmental & Applied Chemistry, College of Chemistry, Central China Normal University, Wuhan, 430079, PR China
语种:
英文
关键词:
Hydrated electron;Integrated oxidation and reduction;Nitrate;Perfluorooctanoic acid;Reactive nitrogen species
期刊:
Environmental Pollution
ISSN:
0269-7491
年:
2022
卷:
313
页码:
120172
基金类别:
This work was supported by National Science Foundation of China (Grant No. 22076057 , 21777052 ), National Key R&D Program of China (Grant 2018YFC1802003 ), the Project for Application Foundation Frontier for Wuhan (Grant 2019020701011486 ), and The Program of Introducing Talents of Discipline to Universities of China ( 111 program, B17019 ).
机构署名:
本校为第一机构
院系归属:
化学学院
摘要:
A significantly accelerated defluorination of recalcitrant perfluorooctanoic acid (PFOA) was explored with the co-present nitrate (20 mg L−1) by UV/sulfite treatment (UV/sulfite-nitrate). The deep defluorination of PFOA and complete denitrification of nitrate were simultaneously achieved in UV/sulfite-nitrate system. At the initial 30 min, PFOA defluorination exhibited an induction period, exactly corresponding to the removal of the co-existed nitrate. Upon the induction period passed, an accelerated removal of PFOA (5 mg L−1) occurred, nearl...

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