期刊论文

Lu, Liang-Qiu;Xiao, Wen-Jing

英文

Trends in Chemistry

2589-5974

2020

2

8

764-775

10.1016/j.trechm.2020.06.002

National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21772052, 21772053, 21822103, 21820102003, 91956201]; Program of Introducing Talents of Discipline to Universities of China (111 Program) [B17019]; Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2017AHB047]

本校为第一且通讯机构

Transition metal-catalyzed allylations are among the most important tools for the formation of chemical bonds. Unlike soft nucleophiles (pKa < 25), reactions of hard nucleophiles (pKa > 25) usually suffer from requiring organometallic reagents or the use of strong bases. In addition, traditional single-electron allylations always require rigorously controlled reaction conditions as well as the use of a stoichiometric reductant that often reduces functional group tolerance. Single-electron allylation reactions facilitated by synergistic tr...