NiFe alloys and metal-nitrogen-carbon materials (M-N-C, M = Ni, Fe, Co, etc.) are foremost catalysts in the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) process, respectively. Nevertheless, the monotonic performance and insufficient stability hinder their practical application in rechargeable batteries. Herein, we simultaneously combine Ni(Fe)OOH and Ni/Fe-N-C active sites together into 3D interconnected core-shell nanochains (Ni2Fe1@PANI-KOH900). The obtained catalyst exhibits robust activity and durability in both OER a...