[Xu, Hao; Qian, Wei-Feng; He, Jin-Yu; Zhu, Cuiju; Zhong, Bing] Cent China Normal Univ, CCNU uOttawa Joint Res Ctr, Key Lab Pesticides & Chem Biol, Minist Educ,Coll Chem,Int Joint Res Ctr Intellige, Wuhan 430079, Peoples R China.
通讯机构：
[Cuiju Zhu; Hao Xu] C
CCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticides & Chemical Biology of Ministry of Education, International Joint Research Center for Intelligent Biosensing Technology and Health, College of Chemistry, Central China Normal University, Wuhan 430079, PR China
语种：
英文
关键词：
Bioactive compounds;C(sp(3))−H oxygenation;Electrochemical;Phenols;Water as oxygen source
Generous financial support from the National Natural Science Foundation of China ( 21801087 ).
机构署名：
本校为第一机构
院系归属：
化学学院
摘要：
Electrochemical C(sp3) -H oxygenation of phenols derivatives were accomplished using H2O as the sole oxygen source. Thus, selectively oxidative 4-cresols to 4-acylphenols derivatives proved viable with the aid of indirect electrolysis, through metal-and external oxidant free environmental-friendly and safe electrocatalytic condi-tions. Advances of this strategy were proved by its ability to transform various sulfonamides with excellent site and regioselectivity. Detailed mechanistic studies allowed to delineate the exact profile of the generation of the...
