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Synthesis, light-emitting and optical limiting properties of new donor–acceptor conjugated polymers derived from 3,5-dicyano-2,4,6-tristyrylpyridine

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成果类型:
期刊论文
作者:
Wang, Hongli;Li, Zhen;Huang, Bin;Jiang, Zuoquan;Liang, Yanke;...
通讯作者:
Qin, Jingui
作者机构:
[Qin, Jingui] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China.
Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Organ Solids, Beijing 100080, Peoples R China.
Harbin Inst Technol, Dept Phys, Harbin 150001, Peoples R China.
Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Qin, Jingui] W
Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China.
语种:
英文
关键词:
3,5-Dicyano-2,4,6-tristyrylpyridine;Electroluminescence;Knoevenagel reaction;Light-emiting diodes (LEDs);Optical limiting;Poly(9-vinylcarbazole) (PVK)
期刊:
Reactive and Functional Polymers
ISSN:
1381-5148
年:
2006
卷:
66
期:
9
页码:
993-1002
机构署名:
本校为其他机构
院系归属:
化学学院
摘要:
Three donor-acceptor conjugated polymers P1-P3 derived from 3,5-dicyano-2,4,6-tristyrylpyridine (PY) have been synthesized through the Knoevenagel reaction. The polymers are characterized by 1H NMR, FTIR, UV-vis and elemental analysis. P1 and P2 have high molecular weight up to 2.3 ×105 and 29.5 ×105 and show excellent solubility in common solvents such as THF, CH2Cl2, CHCl3 and DMF. They all have relatively good thermal stability with the 5% weight loss temperature at 402, 264 and 364 °C in argon, respectively. The fluorescence spectrum of P1 displayed the maximum at 588 nm in...

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