期刊论文

Ai, Zhihui;Zhang, Lizhi

英文

Chemical Engineering Journal

1385-8947

2018

335

720-727

10.1016/j.cej.2017.10.180

National Key Research and Development Program of China [2016YFA0203000]; National Natural Science Funds for Distinguished Young ScholarsNational Natural Science Foundation of China (NSFC)National Science Fund for Distinguished Young Scholars [21425728]; National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21477044, 21777050]; Self-Determined Research Funds of CCNU from the Colleges' Basic Research and Operation of MOE [CCNU14Z01001, CCNU16A02029, CCNU14KFY002]; 111 ProjectMinistry of Education, China - 111 Project [B17019]; Excellent Doctoral Dissertation Cultivation Grant from Central China Normal University [2017YBZZ018]

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In general, the final product of atrazine (ATR) degradation by reactive oxygen species is cyanuric acid bearing a stable s-triazine ring, which is not further oxidized under mild conditions. In this study, we demonstrate that the presence of Ni(II) can increase the aerobic ATR degradation rate of core–shell Fe@Fe2O3 nanowires (CSFN) by 6 times and also achieve the cleavage of recalcitrant s-triazine ring. The cleavage of s-triazine ring in this novel system was confirmed by the measurements of formic acid and nitrite acid. On the basis of expe...