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Space-confined through-space charge-transfer emitters based on CN-substituted fluorene acceptors: Design, synthesis, and thermally-activated delayed fluorescence

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成果类型:
期刊论文
作者:
Li, Yibo;Song, Yongjun;Zhang, Ke;Xiu, Yue;Wang, Pingping;...
通讯作者:
He, L
作者机构:
[Zhang, Ke; Tian, Mingxing; Song, Yongjun; He, L; Li, Yibo; Wang, Pingping; Xiu, Yue; He, Lei] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ,Hubei Int Sci & Technol Cooperat Base, Wuhan 430079, Peoples R China.
通讯机构:
[He, L ] C
Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ,Hubei Int Sci & Technol Cooperat Base, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Through -space charge -transfer;Space -confined;Thermally -activated delayed fluorescence;Cyano-substituted fluorene;Organic light -emitting diode
期刊:
Dyes and Pigments
ISSN:
0143-7208
年:
2023
卷:
219
页码:
111572
基金类别:
We thank the Fundamental Research Funds for the Central Universities (Grant No. CCNU22QN008 ) and the Program of Introducing Talents of Discipline to Universities of China (111 Program, B17019 ) for financial support.
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Space-confined through-space charge-transfer (TSCT) emitters have been extensively explored for developing thermally-activated delayed fluorescence (TADF), but their donor/acceptor units need to be expanded for tuning the emission properties. Herein we report TSCT-TADF emitters 1–3 by chemically fixing cyano-substituted fluorenes as the acceptors. For 1 and 2, 9H-fluorene-2,5-dicarbonitrile (2,5-CN-FL) and 9H-fluorene-2,7-dicarbonitrile (2,7-CN-FL) are used as the acceptors, respectively, and 1,3,6,8-tetramethyl-9H-carbazole is used as the don...

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