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Fermi-level-tuned MOF-derived N-ZnO@NC for photocatalysis: A key role of pyridine-N-Zn bond

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成果类型:
期刊论文
作者:
Huang, Zheao;Zhou, Qiancheng;Wang, Jieming;Yu, Ying
通讯作者:
Yu, Y
作者机构:
[Yu, Ying; Huang, Zheao; Wang, Jieming; Zhou, Qiancheng] Cent China Normal Univ, Coll Phys Sci & Technol, Inst Nanosci & Nanotechnol, Wuhan 430079, Peoples R China.
通讯机构:
[Yu, Y ] C
Cent China Normal Univ, Coll Phys Sci & Technol, Inst Nanosci & Nanotechnol, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
MOF-derived material;Fermi level;Pyridine-N-Zn;DFT calculations;Photocatalysis
期刊:
材料科学技术(英文版)
ISSN:
1005-0302
年:
2022
卷:
112
期:
17
页码:
68-76
基金类别:
Fundamental Research Funds for the Central Universities National Natural Science Foundation of China#&#&#51872108#&#&#U20A20246 Fundamental Research Funds for the Central Universities#&#&#CCNU20TS006
机构署名:
本校为第一且通讯机构
院系归属:
物理科学与技术学院
摘要:
For photocatalytic materials, the composites formed by metal oxides and heteroatom-doped carbon have outstanding activity. Among them, metal-organic framework (MOF) derived composites, usually composed of metal oxide and nitrogen-doped carbon, is not only simple to prepare, but also have far-exceeding catalytic performance than homogenous semiconductor. However, the relationship between the structure and performance in the photocatalytic system is still not clear. Here, we explored the tunable nitrogen configurations in sample N-ZnO@NC by controlling the thermal conversion of ZIF-8. Crucially,...

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