期刊论文

Wu, Yan-Dong;Wu, An-Xin

英文

Organic Chemistry Frontiers

2052-4110

2019

6

14

2534-2538

10.1039/c9qo00570f

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21472056, 21602070, 21772051]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [CCNU15ZX002, CCNU18QN011]; 111 ProjectMinistry of Education, China - 111 Project [B17019]

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A switchable procedure for the synthesis of α-ketoamides and 2-acyloxazoles from aryl methyl ketones and thiocyanate salts is reported. This work discloses the first example of thiocyanate salts being used as amino surrogates via CN bond cleavage. This work enriches the applications of thiocyanate salts beyond limited use as 'SCN', 'CN', or 'S' resources. Furthermore, this work opens a fruitful avenue for the synthesis of α-ketoamides and 2-acyloxazoles in a process with additive-con...