A WELL-DEFINED CYCLOTRIPHOSPHAZENE-BASED EPOXY MONOMER AND ITS APPLICATION AS A NOVEL EPOXY RESIN: SYNTHESIS, CURING BEHAVIORS, AND FLAME RETARDANCY

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作者信息关键词期刊信息基础信息归属信息摘要

成果类型：

期刊论文

作者：

You, Geyun;Cai, Zhe;Peng, Hao;Tan, Xiaosong;He, Hongwu*

通讯作者：

He, Hongwu

作者机构：

[He, Hongwu; Peng, Hao; You, Geyun; Tan, Xiaosong; Cai, Zhe] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China.

[He, Hongwu] Cent China Normal Univ, Coll Chem, 152 Luoyu Rd, Wuhan 430079, Peoples R China.

通讯机构：

[He, Hongwu] C

Cent China Normal Univ, Coll Chem, 152 Luoyu Rd, Wuhan 430079, Peoples R China.

语种：

英文

关键词：

Curing behavior;Cyclotriphosphazene;Epoxy resin;Flame retardancy;Organophosphorus

期刊：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS

ISSN：

1042-6507

年：

2014

卷：

189

期：

页码：

541-550

DOI：

10.1080/10426507.2013.829838

基金类别：

National Engineering Research Center of Phosphate Resources Development and Utilization [2012k011]

机构署名：

本校为第一且通讯机构

院系归属：

化学学院

摘要：

A novel cyclotriphosphazene-based epoxy monomer, hexa-[4-(glycidyloxycarbonyl) phenoxy]cyclotriphosphazene (HGCP), was synthesized via a four-step synthetic route, and fully characterized by 1H, 13C, and 31P NMR spectroscopy, high-resolution mass spectrometry, and elemental analysis. Thermosetting systems based on HGCP with three curing agents, for example, 4,4′-diaminodiphenylsulfone (DDS), 4,4′-diaminodiphenylmethane (DDM), and dicyandiamide (DICY), were used for making a comparison of their thermal curing behaviors. The curing behaviors we...

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A WELL-DEFINED CYCLOTRIPHOSPHAZENE-BASED EPOXY MONOMER AND ITS APPLICATION AS A NOVEL EPOXY RESIN: SYNTHESIS, CURING BEHAVIORS, AND FLAME RETARDANCY

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