Photo-switchable In(III)-to-In(I) site on oxygen vacancy-laden BiOCl surface for selective degradation of monocyclic aromatic compounds

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成果类型：

期刊论文

作者：

Ge, Suxiang;Wang, Yafei;Song, Panting;Zhan, Guangming;Liu, Chunhui;...

通讯作者：

Zheng, Z;Mao, CL

作者机构：

[Liu, Chunhui; Li, Dapeng; Wang, Yafei; Zheng, Zhi; Zheng, Z; Song, Panting; Ge, Suxiang] Xuchang Univ, Inst Surface Micro & Nano Mat, Coll Chem & Mat Engn, Key Lab Micronano Energy Storage & Convers Henan P, Xuchang 461000, Henan, Peoples R China.

[Zhang, Lizhi; Mao, Chengliang; Mao, CL; Zhan, Guangming] Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, Shanghai 200240, Peoples R China.

[Zhang, Lizhi; Mao, Chengliang; Zhan, Guangming] Cent China Normal Univ, Inst Environm & Appl Chem, Coll Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.

[Ding, Xing] Huazhong Agr Univ, Coll Sci, Wuhan 430070, Peoples R China.

通讯机构：

[Mao, CL ] S

[Zheng, Z ] X

Xuchang Univ, Inst Surface Micro & Nano Mat, Coll Chem & Mat Engn, Key Lab Micronano Energy Storage & Convers Henan P, Xuchang 461000, Henan, Peoples R China.

Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, Shanghai 200240, Peoples R China.

语种：

英文

关键词：

In(I) dopant;BiOCl;Oxygen vacancies;Monocyclic aromatic compounds;Selective degradation

期刊：

Separation and Purification Technology

ISSN：

1383-5866

年：

2023

卷：

326

页码：

124716

DOI：

10.1016/j.seppur.2023.124716

基金类别：

CRediT authorship contribution statement Suxiang Ge: Conceptualization, Data curation, Formal analysis, Investigation, Writing – original draft. Yafei Wang: Data curation, Validation. Panting Song: Data curation, Validation. Guangming Zhan: Data curation, Validation. Chunhui Liu: Data curation, Validation. Xing Ding: Data curation, Validation. Dapeng Li: Data curation, Validation. Chengliang Mao: Supervision, Visualization, Investigation, Writing – review & editing, acquisition. Zhi Zheng: Supervision, Visualization,

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本校为其他机构

院系归属：

化学学院

摘要：

Enrichment of OVs on oxide semiconductors is an effective strategy to promote their photocatalytic performances but limited by the maximum concentration allowed by lattice thermodynamics. Herein, we report that an In(I) doping strategy, realized by an UV light-induced reduction of a sluggish In(III) precursor, can promote OVs-laden BiOCl by up to 6.5 times for the visible-light sodium pentachlorophenate (PCPNa) degradation. The photocatalysis mechanism study highlighted the In(I) site as an electron transfer site could reduce PCPNa directly, related to the In(I) induced more negative conductio...

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Photo-switchable In(III)-to-In(I) site on oxygen vacancy-laden BiOCl surface for selective degradation of monocyclic aromatic compounds

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