Both the title mol-ecular adducts of 2-methyl-aniline or 2,5-dichloro-aniline with picric acid are 1:1 organic salts, namely 2-methyl-anilinium picrate, C7H10N+· C6H2N3O7 -, (I), and 2,5-dichloro-anilinium picrate, C6H6Cl2N +·C6H2N3O7 -, (II). In both structures, the phenoxide O atoms accept two N - H hydrogen bonds in a bifurcated acceptor fashion, which link the component ions by N - H&mellip;O hydrogen bonds into continuous two-dimensional zigzag layers, running parallel to the (100) plane in (I) and the (010) plane in (II). A π-πinter-action is observed between symmetry-r...