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Fluorocarbon-hydrocarbon hybrid cationic surfactants: Synthesis, surface-activity properties and anti-corrosion performance

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成果类型:
期刊论文
作者:
Nuer, Maimaiti;Duan, Jiang*;Wei, Zengfeng;Wu, Wenhai;Ma, Jianxiang;...
通讯作者:
Duan, Jiang;Zhang, Aidong(张爱东
作者机构:
[Zhang, Aidong; Ma, Jianxiang; Duan, Jiang; Wei, Zengfeng; Wu, Wenhai; Nuer, Maimaiti] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Duan, J; Zhang, AD] C
Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Biophysics;Chlorine compounds;Contact angle;Corrosion inhibitors;Corrosion prevention;Critical micelle concentration;Dyes;Electrochemical corrosion;Electrochemical impedance spectroscopy;Hydrocarbons;Isotherms;Micelles;Polarization;Potentiodynamic polarization;Steel corrosion;Anticorrosion performance;Corrosion inhibition;Fluoro-surfactant;Hydrocarbon surfactants;Inhibition efficiency;Langmuir isotherm models;Surface activities;Surface characterization;Cationic surfactants
期刊:
Journal of Molecular Liquids
ISSN:
0167-7322
年:
2020
卷:
306
页码:
112897
基金类别:
This work has been financially supported by the National Natural Science Foundation of China (21772060), and the Wuhan Municipal Front Program for Application Basis Research, Hubei Province, PR China (2018010401011283). This work has been financially supported by the National Natural Science Foundation of China ( 21772060 ), and the Wuhan Municipal Front Program for Application Basis Research , Hubei Province, PR China ( 2018010401011283 ).
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Fluorocarbon-hydrocarbon hybrid cationic surfactants possess unique performance because they combine the characteristics of fluorocarbon and hydrocarbon surfactants, however, their potential as metal corrosion inhibitors has not been addressed. Here, two hybrid cationic surfactants (F4H6 and F6H6) were synthesized using perfluorobutylsulfonyl and perfluorohexylsulfonyl chains, respectively, through a cationic bridge of N-benzyl-N',N'-dimethyl ethylenediamine, to connect with a hexyl group as the hydrocarbon chain. Both F4H6 and F6H6 exhibited low critical micelle concentrations as 1.81 x 10(-3...

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