Commercial Ni foam (NF) was utilized as a substrate featuring its high electrical conductivity, good mechanical strength, 3D skeleton with large surface area for catalysts loading[13], [14], [15] and low cost. The NiFe-Pi/P@NF integrated electrode was prepared via a facile and green one-pot electrodeposition approach (Fig. 1a), after rising with pure water, the electrode was dried under atmosphere naturally. For the electrolyte, NiCl2 and FeCl3 were served as the bimetal sources, and NaH2PO2