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High rate performances of the cathode material LiNi1/3Co1/3Mn1/3O2 synthesized using low temperature hydroxide precipitation

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成果类型:
期刊论文
作者:
Cheng, Cuixia;Tan, Long;Liu, Haowen;Huang, Xintang*
通讯作者:
Huang, Xintang
作者机构:
[Huang, Xintang; Cheng, Cuixia] Cent China Normal Univ, Dept Phys, Ctr Nanosci & Technol, Wuhan 430079, Peoples R China.
[Tan, Long; Liu, Haowen] S Cent Univ Nationalities, Wuhan 430074, Peoples R China.
[Liu, Haowen] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China.
通讯机构:
[Huang, Xintang] C
Cent China Normal Univ, Dept Phys, Ctr Nanosci & Technol, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
A. Layered compounds;B. Chemical synthesis;C. X-ray diffraction;D. Electrochemical properties
期刊:
Materials Research Bulletin
ISSN:
0025-5408
年:
2011
卷:
46
期:
11
页码:
2032-2035
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [50872039]; South-Central University for Nationalities [CZZ10002]; 973 Project of ChinaNational Basic Research Program of China [2011CB935901]
机构署名:
本校为第一且通讯机构
院系归属:
物理科学与技术学院
摘要:
A low-temperature reaction route is introduced based on hydroxide precipitation method to synthesize the cathode material LiNi 1/3Co1/3Mn1/3O2. The crystal structure and morphology of the prepared powder have been characterized by X-ray diffraction and Scan electron microscope, respectively. The charge-discharge tests were performed between 2.5 and 4.5 V. The discharge capacity of the material is strongly impacted by the reaction temperature. The powders sintered at 850 °C show the best electrochemical performance and the initial discharge capacity is about 160 mAh g-1 at 5 C. Powder X-ray...

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