Enantioselective Di-/Perfluoroalkylation of β-Ketoesters Enabled by Cooperative Photoredox/Nickel Catalysis

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成果类型：

期刊论文

作者：

Liu, Jing;Ding, Wei;Zhou, Quan-Quan;Liu, Dan;Lu, Liang-Qu*;...

通讯作者：

Lu, Liang-Qu;Xiao, Wen-Jing

作者机构：

[Lu, Liang-Qu; Xiao, WJ; Liu, Jing; Xiao, Wen-Jing; Zhou, Quan-Quan; Ding, Wei; Liu, Dan] Cent China Normal Univ, Coll Chem, Hubei Int Sci & Technol Cooperat Base Pesticide &, Key Lab Pesticide & Chem Biol,Minist Educ, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.

[Xiao, Wen-Jing] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China.

通讯机构：

[Lu, LQ; Xiao, WJ] C

[Xiao, Wen-Jing] L

Cent China Normal Univ, Coll Chem, Hubei Int Sci & Technol Cooperat Base Pesticide &, Key Lab Pesticide & Chem Biol,Minist Educ, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.

Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China.

语种：

英文

期刊：

Organic Letters

ISSN：

1523-7060

年：

2018

卷：

期：

页码：

461-464

DOI：

10.1021/acs.orglett.7b03826

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21472057, 21572074, 21772052, 21772053]; Program of Introducing Talents of Discipline to Universities of ChinaMinistry of Education, China - 111 Project [B17019]

机构署名：

本校为第一且通讯机构

院系归属：

化学学院

摘要：

Efficient and enantioselective radical difluoroalkylation and perfluoroalkylation reactions of β-ketoesters were successfully developed through an asymmetric photoredox and nickel catalysis cascade. This protocol provides Rf-containing quaternary stereocenters in up to 67% yield and 95:5 er with ethyl iododifluoroacetate and perfluoroalkyl iodides (C3F7I and C4F9I) a...

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Enantioselective Di-/Perfluoroalkylation of β-Ketoesters Enabled by Cooperative Photoredox/Nickel Catalysis

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