Dynamic Activation of Adsorbed Intermediates via Axial Traction for the Promoted Electrochemical CO2 Reduction

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成果类型：

期刊论文

作者：

Wang, Xinyue;Wang, Yu;Sang, Xiahan;Zheng, Wanzhen;Zhang, Shihan*;...

通讯作者：

Hou, Yang;Qiu, Ming;Zhang, Shihan;Wu, Gang

作者机构：

[Lei, Lecheng; Zheng, Wanzhen; Yang, Bin; Li, Zhongjian; Wang, Xinyue; Hou, Yang] Zhejiang Univ, Key Lab Biomass Chem Engn, Minist Educ, Coll Chem & Biol Engn, Hangzhou 310027, Peoples R China.

[Shuai, Ling; Qiu, Ming] Cent China Normal Univ, Coll Phys Sci & Technol, Inst Nanosci & Nanotechnol, Wuhan 430079, Peoples R China.

[Zhang, Shihan; Chen, Jianmeng] Zhejiang Univ Technol, Coll Environm, Hangzhou 310027, Peoples R China.

[Wang, Yu] Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China.

[Sang, Xiahan] Wuhan Univ Technol, Nanostruct Res Ctr, Wuhan 430070, Peoples R China.

通讯机构：

[Hou, Yang; Zhang, Shihan] Z

[Qiu, Ming] C

[Wu, Gang] S

[Hou, Yang] I

Zhejiang Univ, Key Lab Biomass Chem Engn, Minist Educ, Coll Chem & Biol Engn, Hangzhou 310027, Peoples R China.

语种：

英文

关键词：

axial traction;dynamic understanding;electrochemical CO2RR;single-atom catalysts

期刊：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ISSN：

1433-7851

年：

2021

卷：

期：

页码：

4192-4198

DOI：

10.1002/anie.202013427

基金类别：

This work was financially supported by the National Natural Science Foundation of China (21922811, 51702284, 21878270, and 21961160742), Zhejiang Provincial Natural Science Foundation of China (LR19B060002 and LR19E080001), the Fundamental Research Funds for the Central Universities, the Startup Foundation for Hundred‐Talent Program of Zhejiang University, the Fundamental Research Funds for the Central Universities CCNU20ZT003. We thank BL10B endstation of Hefei Lightsource, BL14W1 beamline in Shanghai and Beijing Synchrotron Radiation Facility (SSRF) for XAS measurements. G. Wu acknowledges the support from National Science Foundation (CBET‐1604392, 1804326).

机构署名：

本校为通讯机构

院系归属：

物理科学与技术学院

摘要：

Regulating the local environment and structure of metal center coordinated by nitrogen ligands (M-N4) to accelerate overall reaction dynamics of the electrochemical CO2 reduction reaction (CO2RR) has attracted extensive attention. Herein, we develop an axial traction strategy to optimize the electronic structure of the M-N4 moiety and construct atomically dispersed nickel sites coordinated with four nitrogen atoms and one axial oxygen atom, which are embedded within the carbon matrix (Ni-N4-O/C). The Ni-N4-O/C electrocatalyst exhibited excellen...

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Dynamic Activation of Adsorbed Intermediates via Axial Traction for the Promoted Electrochemical CO2 Reduction

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