期刊论文

中文

高等学校化学学报

0251-0790

1996

17

12

1869-1873

国家自然科学基金,湖北省自然科学基金

本校为第一机构

通过３－羟甲苯苯并恶唑酮与金属钠的反应制取基钠盐，利用钠盐同α－氯代乙酰氧基烃基膦酸酯反应合成２１个未见报道的α－烃基磷酸酯类化合物，确定了产物的结构，考察了反应条件，探讨了可能的反应机理。

Twenty-one new phosphorus compounds were synthesized by the reaction of O,O-dialkyl-alpha-chloroacetoxyalkyl phosphonates and sodium salt of 3-hydroxymethylbenzoxazolone. Their structures were confirmed by means of elementary analysis, IR, H-1 and P-31 NMR and MS. The possible mechanism is that the unsteady reactive intermediate reacting from reactants undergoes intramolecular elec...