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Synthesis and Herbicidal Activities of 2-Methylpropan-2-aminium O-Methyl l-(Substituted Phenoxyacetoxy)alkylphosphonates

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成果类型:
期刊论文
作者:
Peng Hao;Deng Xiaoyan;Gao Ling;Tan Xiaosong;He Hongwu*
通讯作者:
He Hongwu
作者机构:
[Gao Ling; Deng Xiaoyan; Peng Hao; He Hongwu; Tan Xiaosong] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[He Hongwu] C
Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Herbicidal activity;Phosphonate;2-Methylpropan-2-aminium
关键词(中文):
乙酰氧基;除草活性;取代苯;烷基;合成;二氯苯氧乙酸;标题化合物;膦
期刊:
高等学校化学研究:英文版
ISSN:
1005-9040
年:
2014
卷:
30
期:
1
页码:
82-86
基金类别:
——————————— *Corresponding author. E-mail: he1208@mail.ccnu.edu.cn Received May 7, 2013; accepted June 5, 2013. Supported by the National Basic Research Program of China(No.2010CB126100), the National Key Technologies R&D Progaram of China(No.2011BAE06B03), the National Natural Science Foundation of China(No.21172090) and the Program for Changjiang Scholars and Innovative Research Team in University, China(No.IRT0953). © Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
A series of 2-methylpropan-2-aminium O-methyl 1-(substituted phenoxyacetoxy)alkylphosphonates (5a-5o) was selectively synthesized by reacting the corresponding O,O-dimethyl 1-(substituted phenoxyacetoxy)-alkylphosphonates with an excess of 2-methylpropan-2-amine. The results of preliminary bioassays show that the title compounds exhibit moderate to good herbicidal activities against Brassica napus and Echinochloa crusgalli. Furthermore, compounds 5a-5j, which show much higher activities than compounds 5k-5o, were selected to further evaluate th...

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